Silicon holds fourteen protons although aluminium holds only thirteen. Therefore, the nuclear charge of silicon is bigger than that of aluminium, implying which the electrons during the 3p orbital of silicon will experience a simpler nuclear charge than aluminium.
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Among p-orbitals, 4p orbitals are the farthest within the nucleus with the bromine atom with (+35) demand. Consequently, the electrons that reside during the 4p orbital are those to encounter the bottom effective nuclear cost. These electrons are shielded by electrons that happen to be existing in the 2p and 3p orbitals together with the s-orbitals.
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